Clean and selective catalytic C-H alkylation of alkenes with environmental friendly alcohols
نویسندگان
چکیده
منابع مشابه
O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols.
The efficiency and selectivity of hydrogen atom transfer from organic molecules are often difficult to control in the presence of multiple potential hydrogen atom donors and acceptors. Here, we describe the mechanistic evaluation of a mode of catalytic activation that accomplishes the highly selective photoredox α-alkylation/lactonization of alcohols with methyl acrylate via a hydrogen atom tra...
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ژورنال
عنوان ژورنال: Molecular Catalysis
سال: 2017
ISSN: 2468-8231
DOI: 10.1016/j.molcata.2016.09.010